WebbElectronic interaction of the -NMe(2) group with the conjugated ligand backbone can be inferred from structural and spectroscopic data. The new yttrium guanidinate complex 1 and its related amidinate analogue [PhC(NAr)(2)]Y(CH(2)SiMe(3))(2)(THF) (2) are highly active and selective catalysts for alkene hydrosilylation with PhSiH(3) (tof > 600 h(-1) at … WebbShaozhong Ge. Pd-catalyzed α-arylation of α, α-difluoroketones with aryl bromides and chlorides. A route to difluoromethylarenes. Scandium, yttrium, and lanthanum benzyl and …
GE Shaozhong - NUS Chemistry NUS Chemistry
WebbCaizhi Wu a and Shaozhong Ge *a Author affiliations Abstract We report a stereoselective regiodivergent hydroboration of aryl,alkyl-disubstituted internal allenes with pinacolborane (HBpin) in the presence of cobalt catalysts generated from bench-stable Co (acac) 2 and bisphosphine ligands. Webb8 mars 2024 · Corresponding Author. Prof. Dr. Shaozhong Ge [email protected] orcid.org/0000-0003-1045-1940; Department of Chemistry, National University of … css footer bottom of screen
Enantioselective Copper‐Catalyzed Alkylation of Quinoline …
WebbShaozhong Ge View Recently, the Ge group realized a metal-catalyzed variant with a reaction sequence comprising allene dimerization (forming I 12 ) and hydroboration … WebbShaozhong Ge An asymmetric cobalt‐catalyzed hydroboration/cyclization of 1,7‐enynes to synthesize chiral six‐membered N‐heterocyclic compounds was developed. A variety of … Webb6 okt. 2024 · 47. Palladium-Catalyzed Enantioselective α-Arylation of α-Fluoroketones. Zhiwei Jiao, Jason Beiger, Yushu Jin, Shaozhong Ge, Jianrong Steve Zhou,* John F. Hartwig* (Two groups contributed different procedures with complementary scopes) J. Am. Chem. Soc. 2016, 138, 15980. DOI: 10.1021/jacs.6b09580. Published on 6 Nov 2016. earle ann arbor mi